Particle in a box  (infinite square well)

A particle confined to a box with infinite walls (V = 0 inside, ∞ outside). Switch between one particle in 1D, one particle in 2D, two non-interacting particles in 1D, and two interacting particles in 1D (screened Coulomb, solved numerically). The 2D and two-free-particle cases share the same product wavefunction (x,y ↔ x₁,x₂); turning on interaction breaks that factorization and produces correlation. Lengths are in units of the box length L (= 1), energies in units of h²/8mL².

C = 3.0

Energy levels  

Wavefunction  ψn(x)  and density  |ψn(x)|²

ψn(x) — amplitude (n−1 interior nodes)

|ψn(x)|² — probability density

Wavefunction

ψ — signed (nodal lines)

|ψ|² — probability density

3D surface — drag to rotate

Joint vs single-particle probability  — is there correlation?

x₁ = 0.50 L

particle 1: |φn₁(x₁)|² (where it is found, dashed)

particle 2: marginal |φn₂(x₂)|² and conditional P(x₂|x₁)